Bis(1,2,3,4-tetrahydroquinolin-6-yl)methane
نویسندگان
چکیده
The asymmetric unit of the title compound, C(19)H(22)N(2), contains one half-mol-ecule. The 1,2,3,4-tetra-hydro-quinoline units are linked by a methyl-ene bridge, which lies on a twofold rotation axis. The non-aromatic ring adopts a flattened-boat conformation. The dihedral angle between the two symmetry-related benzene rings is 64.03 (7)°.
منابع مشابه
Crystal structure of cis-1-(2-methyl-1,2,3,4-tetrahydroquinolin-4-yl)azepan-2-one
In the title compound, C16H22N2O, the azepan-2-one ring adopts a chair conformation, while the 1,2,3,4-tetra-hydro-pyridine ring adopts a half-chair conformation. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming supra-molecular chains propagated along [10-1], with weak C-H⋯O inter-actions occurring between the chains.
متن کاملGold(I) complexes of bisphosphines with bis(azol-1-yl)methane backbone: structure of a rare dinuclear gold(I) complex [(Au2Cl){CH2(1,2-C3H2N2PPh2)2}3Cl].
Gold(i) complexes of bisphosphines assembled on the bis(azol-1-yl)methane platform viz.: bis(2-diphenylphosphinoimidazol-1-yl)methane (1), bis(5-diphenylphosphinopyrazol-1-yl)methane (2), bis(5-diphenylphosphino-1,2,4-triazol-1-yl)methane (3) have been described. Reactions of two equivalents of bisphosphines 1-3 with Au(SMe2)Cl produced dinuclear complexes [(AuCl)2(μ-P^P)] (4-6) with AuAu dista...
متن کاملCrystal structures of bis[2-(pyridin-2-yl)phenyl-κ2 N,C 1]rhodium(III) complexes containing an acetonitrile or monodentate thyminate(1−) ligand
The crystal structures of bis-[2-(pyridin-2-yl)phen-yl]rhodium(III) complexes with the metal in an octahedral coordination containing chloride and aceto-nitrile ligands, namely (OC-6-42)-aceto-nitrile-chlorido-bis-[2-(pyridin-2-yl)phenyl-κ(2) N,C (1)]rhodium(III), [RhCl(C11H8N)2(CH3CN)] (1), thyminate(1-) and methanol, namely (OC-6-42)-methanol(5-methyl-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidin-1-...
متن کاملμ3-Oxido-tris{dichlorido[1,3-bis(1,3,5-trimethylphenyl)imidazol-2-ylidene]gold(III)} bis(trifluoromethanesulfonyl)imide–[bis(trifluoromethanesulfonyl)imide]silver(I) (1/2)
The unusual trinuclear Au(III) oxide title complex, [Au(3)Cl(6)O(C(21)H(24)N(2))(3)](C(2)F(6)NO(4)S(2))·2[Ag(C(2)F(6)NO(4)S(2))], is the side product of the reaction of [1,3-bis-(1,3,5-trimethyl-phen-yl)imidazol-2-yl-idene]dichloridophenyl-gold(III) with silver bis-(trifluoro-methane-sulfon-yl)imide in the presence of traces of water. In contrast to corresponding Au(I) complexes, the core struc...
متن کاملBis{1-[(1H-benzimidazol-1-yl)methyl-κN 3]-1H-1,2,3,4-tetrazole}silver(I) nitrate
In the title salt, [Ag(C(9)H(8)N(6))(2)]NO(3), the central Ag(I) atom is linearly coordinated by the N atoms [171.97 (8)°] from two 1-[(benzimidazol-1-yl)meth-yl]-1H-1,2,3,4-tetra-zole ligands. The benzimidazole rings in adjacent mol-ecules are parallel with an average inter-planar distance of 3.461 Å; adjacent mol-ecules are linked through N-H⋯O hydrogen bonds into a linear chain along the b-a...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008